that 引导先行词是人或物的定语从句,且关系词在句中可作主语和宾语。The gril that is sitting in the classroom is a my sister.whom谁,用在当先行词是指人的定语从句中,而且关系词在句中作宾语,eg:He is a boy whom we went with there他是和我们一起去那儿的那个男孩。